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New Perspective on the Phase Diagram of Cuprate High-Temperature Superconductors

机译:铜酸盐高温相图的新视角   超导体

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摘要

Universal scaling laws can guide the understanding of new phenomena, and forcuprate high-temperature superconductivity such an early influential relationshowed that the critical temperature of superconductivity ($T_c$) correlateswith the density of the superfluid measured at low temperatures. This famousUemura relation has been inspiring the community ever since. Here we show thatthe charge content of the bonding orbitals of copper and oxygen in theubiquitous CuO$_2$ plane, accessible with nuclear magnetic resonance (NMR), istied to the Uemura scaling. This charge distribution between copper and oxygenvaries between cuprate families and with doping, and it allows us to draw a newphase diagram that has different families sorted with respect to their maximum$T_c$. Moreover, it also shows that $T_c$ could be raised substantially if wewere able to synthesize materials in which more oxygen charge is transferred tothe approximately half filled copper orbital.
机译:通用尺度定律可以指导对新现象的理解,并建立了高温超导性,这种早期的影响关系表明,超导性的临界温度($ T_c $)与在低温下测得的超流体的密度相关。从那以后,这种著名的植村关系一直在激励着社区。在这里,我们表明,在整个CuO $ _2 $平面中,铜和氧键合轨道的电荷含量可通过核磁共振(NMR)访问,与上村定标有关。铜和氧之间的电荷分布在铜酸盐系列之间以及掺杂之间变化,并且它使我们能够绘制一个新相图,该图具有关于其最大$ T_c $排序的不同族。此外,它还表明,如果我们能够合成其中更多的氧电荷转移到大约一半填充的铜轨道上的材料,则可以大大提高$ T_c $。

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